JentooChemistry

AP® Chemistry · Unit 1 · Topic 1.5

Coulomb's Law Inside the Atom

Coulomb's law says the attraction between the nucleus and an electron depends on their charges and on 1/distance2, which is why electrons stay bound and why electrons closer to the nucleus are held much more tightly.

Opposite charges attract, and Coulomb's law gives the exact rule: force equals a constant times the product of the two charges, divided by the square of the distance between them. The nucleus is positive, the electron is negative, so there's always a pull holding the electron in. That pull falls off fast with distance, since distance is squared in the denominator. Double the distance and the force doesn't drop by half, it drops to one quarter. Triple it and the force drops to one ninth. That squared relationship is the whole engine behind atomic structure: it decides why electrons settle into layers rather than drifting away.

This is also why a core electron, sitting close to the nucleus, feels a far stronger grip than a valence electron sitting out at the edge of the atom. Small distance means a huge force; large distance means a weak one. That is the mechanical reason core electrons are nearly impossible to remove while valence electrons come and go easily in bonding.

There's a catch for atoms with more than one electron. An outer electron doesn't feel the nucleus's full positive charge, because the electrons sitting between it and the nucleus block, or shield, part of that charge. The outer electron responds to an effective nuclear charge, smaller than the actual number of protons. This shielding idea connects straight into why atomic size, ionization energy, and other periodic trends behave the way they do across a row or down a column.

Key terms

Coulomb's law
The rule that electric force between two charges equals a constant times their charges divided by distance squared.
Shielding
The blocking of nuclear charge from outer electrons by electrons that sit closer to the nucleus.
Effective nuclear charge
The net positive charge an electron actually experiences after shielding is accounted for.
Core electron
An inner electron held tightly because it sits close to the nucleus.
Valence electron
An outer electron held loosely because it sits far from the nucleus and is shielded by inner electrons.

Watch it explained

  1. How it worksHow does the Coulomb force change the moment you double the gap between a proton and an electron?
  2. How it worksWalk me through why a core electron is held harder than a valence electron in the same atom.
  3. Worked exampleCompare the pull on an electron sitting at distance r versus one at 2r from the same nucleus.
  4. Common mistakeWhy doesn't every electron in a many-electron atom feel the full charge of the nucleus?

Check yourself

Your turn1 of 2
An electron feels an attractive Coulomb force from the nucleus at some distance r. If the electron moves to a distance 6 times as far from the nucleus, by what factor does the force change? (Report new force divided by old force.)

End of topic.