AP® Chemistry · Unit 7 · Topic 7.8
Representations of Equilibrium
A particle drawing of equilibrium shows both reactants and products at once, in a ratio set by K, because the forward and reverse reactions never stop running.
Equilibrium isn't a finish line where the reaction stops. It's a container where the forward reaction and the reverse reaction both keep firing, at equal rates, forever. A drawing of that container is a snapshot of real particles that exist at that moment, so it has to show some reactant molecules and some product molecules together, never just one kind. The mix doesn't change over time once equilibrium is reached, even though individual particles keep converting back and forth.
The ratio of dots in the drawing is the whole point: it encodes K. A reaction with a large K (say K = 1000) sits far toward products, so a correct drawing shows mostly product particles with only a few reactants scattered in. A reaction with a small K (say K = 0.001) does the opposite: mostly reactants, with a few product particles mixed in. There is no rule that the numbers should ever come out equal; equal numbers would only happen to match one specific K value, not equilibrium in general. A series of drawings taken over time, before equilibrium is reached, shows the particle counts shifting steadily until they stop changing from one frame to the next. That stopping point is equilibrium.
This connects straight to Le Chatelier's idea: if you draw a container at equilibrium and then inject more reactant particles, the next drawing right after injection just shows more reactant dots added in, with the product count unchanged. Only after time passes does the picture shift again, with some of that extra reactant converting to product until the ratio matches K once more.
Key terms
- Equilibrium constant (K)
- A number that fixes the ratio of product to reactant concentrations (each raised to its coefficient) once a reaction stops changing.
- Dynamic equilibrium
- A state where forward and reverse reactions keep occurring at equal rates, so concentrations stay constant overall.
- Particle diagram
- A drawing that represents a mixture using dots or shapes for individual reactant and product molecules.
- Le Chatelier's principle
- The idea that a system at equilibrium shifts to partly counteract any change imposed on it, like added reactant.
Watch it explained
- How it worksDraw the particle mixtures for a reaction with a large K and one with a small K.
- How it worksHow does a series of drawings over time show a system settling into equilibrium?
- Common mistakeWhy isn't an equilibrium drawing supposed to show equal numbers of each particle?
- Going furtherWhat changes in the drawing right after more reactant is injected into the container?
Check yourself
End of topic.