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AP® Chemistry · Unit 3 · Topic 3.4

The Ideal Gas Law

The ideal gas law, PV = nRT, says pressure, volume, moles, and temperature are locked together for any gas that behaves ideally. Knowing three lets you solve for the fourth.

A gas is just a swarm of particles bouncing around, hitting the walls of their container and each other. Pressure comes from how hard and how often those collisions happen, volume is the space the particles are confined to, moles counts how many particles there are, and temperature measures their average kinetic energy. The ideal gas law, PV = nRT, ties all four together with R, the gas constant, as the conversion factor that makes the units work. Squeeze the volume down and collisions get more frequent, so pressure rises. Heat the gas and the particles move faster, hitting the walls harder, so pressure or volume rises too. That is why a sealed bag of chips puffs up at high altitude: outside pressure drops as you climb, but the gas trapped inside still pushes out just as hard, so the bag expands until the lower outside pressure is matched.

The law assumes particles have no volume themselves and do not attract or repel each other, which is close enough to true for most gases at normal pressures and temperatures. This idea sits right next to the individual gas laws, Boyle's, Charles's, and Avogadro's: each of those is just PV = nRT with two variables held constant. It also connects forward to partial pressures and to using gas data to find molar mass, since rearranging the law lets you solve for whichever quantity you do not know, as long as you have the other three.

Key terms

Ideal gas
A theoretical gas whose particles have no volume and no attractive forces between them.
Gas constant (R)
The proportionality constant in PV = nRT, commonly 0.08206 L atm per mol kelvin.
Molar mass
The mass of one mole of a substance, found from gas data using M = mRT/(PV).
Kelvin scale
The absolute temperature scale, with zero at absolute zero, required for gas law calculations.

Watch it explained

  1. How it worksHow do pressure, volume, moles, and temperature lock together in PV equals nRT?
  2. Worked exampleFind the volume of 2.50 mol of nitrogen gas at 1.20 atm and 350 K.
  3. Worked exampleFind the molar mass of a gas when 0.500 g fills 250 mL at 0.980 atm and 298 K.
  4. Common mistakeWhy isn't it safe to plug degrees Celsius into the ideal gas law?

Check yourself

Your turn1 of 2
Find the volume, in liters, of 3.63 mol of an ideal gas at 2.12 atm and 386 K. (Use R = 0.08206 L atm / (mol K).)

End of topic.