AP® Environmental Science · Unit 7 · Topic 7.4

Atmospheric CO2 and Particulates

Atmospheric CO2 rises every year but wiggles with the seasons because Northern Hemisphere plants breathe in and out with the seasons; particulate matter harms health based on size, with smaller PM2.5 reaching deepest into the lungs.

The Keeling curve, measured atop Mauna Loa since 1958, is the clearest record of rising CO2: a steady climb from about 315 ppm to over 420 ppm today. Zoom in, though, and the line isn't smooth. It saws up and down by about 5-6 ppm every single year. That's because the Northern Hemisphere holds most of Earth's land and forest. Each spring and summer, leaves burst out and photosynthesis pulls CO2 out of the air faster than it goes in, so the curve dips. Each autumn and winter, those leaves die and decompose, respiration and decay release carbon back, and the curve climbs again. The Southern Hemisphere, mostly ocean, can't counteract this because it has far less land biomass cycling with the seasons.

Particulate matter follows a different logic: size decides where it lands in you and how much damage it does. PM10, particles under 10 micrometers, get trapped by nose hairs and mucus in the upper airway. PM2.5, under 2.5 micrometers, slip past those defenses, lodge deep in the alveoli, and can even cross into the bloodstream, reaching the heart and other organs. That's why PM2.5 draws more health concern even when it's the smaller share of total particulate mass.

Not all particulates come from tailpipes or smokestacks. Volcanoes, sea spray, pollen, and windblown dust are natural sources, and a big eruption can inject sulfate aerosols into the stratosphere that reflect sunlight and cool a region for a year or more, Mount Pinatubo in 1991 being the classic case. This topic sits alongside the rest of Unit 7 as the longer-timescale, global counterpart to local smog and inversions: same smokestacks and tailpipes, but now tracked in parts per million over decades and in lung tissue over a lifetime.

Key terms

Keeling curve
The continuous record of atmospheric CO2 concentration measured at Mauna Loa since 1958, showing a rising trend with annual sawtooth wiggles.
PM2.5
Particulate matter smaller than 2.5 micrometers in diameter, small enough to penetrate deep into the lungs and bloodstream.
PM10
Particulate matter smaller than 10 micrometers in diameter, mostly trapped in the nose and upper airway.
Sawtooth pattern
The repeating annual rise and fall in the CO2 curve caused by seasonal photosynthesis and decomposition in the Northern Hemisphere.
Stratospheric aerosols
Fine particles, often sulfates from volcanic eruptions, that linger in the stratosphere and reflect sunlight, cooling the surface below.

Watch it explained

  1. How it worksWalk me through the Keeling curve's sawtooth coming from Northern Hemisphere leaves.
  2. How it worksHow do PM10 and PM2.5 particles get stopped in different parts of the airway?
  3. Going furtherWhat happens to regional temperature when a volcano loads the stratosphere with aerosols?
  4. Common mistakeWhy isn't every particle in the air the product of human burning?

Check yourself

Your turn1 of 2
The Keeling curve shows atmospheric CO2 rising steadily year over year, but zooming in reveals a small sawtooth wiggle of about 7 ppm within each single year. What causes this annual up-and-down pattern layered on top of the long-term rise?

End of topic.