AP® Environmental Science · Unit 6 · Topic 6.6

Nuclear Waste and Radioactive Decay

Radioactive waste loses half its radioactivity every half-life, but "half" never reaches zero, so some isotopes stay dangerous for thousands of years. Half-life math lets you calculate exactly how much is left, or how long decay takes.

Spent nuclear fuel is a mix of radioactive isotopes, each decaying at its own fixed rate called a half-life, the time it takes for half of a sample to break down into something else. Decay is exponential, not linear: you never hit zero, you just keep cutting what remains in half. Some fission products, like cesium-137, have half-lives around 30 years, so after a few centuries they've mostly decayed away. But others, like plutonium-239, have a half-life near 24,000 years. Ten half-lives only gets you to about a thousandth of the original amount, so the waste must be isolated for a time longer than any human institution has existed, far longer than recorded history.

The math is the same every time. Remaining mass equals the starting mass times one-half raised to the number of half-lives elapsed. Run that forward and you get a decay curve, steep at first, then flattening out as there's less material left to decay. Run it backward, solving for time instead of mass, and you get how long a sample takes to fall to some target amount: time equals the half-life times the natural log of the starting-to-remaining ratio, divided by the natural log of 2.

This connects to the rest of the unit because nuclear power's waste problem is the tradeoff for its low-carbon energy output. Spent fuel comes out of a reactor extremely hot and radioactive, cools for years in a water pool as the shortest-lived isotopes decay fast, then still needs dry-cask storage and eventually deep geologic burial for the long-lived remainder.

Key terms

Half-life
The fixed time it takes for half of a radioactive sample's atoms to decay.
Radioactive decay
The spontaneous breakdown of unstable atomic nuclei, releasing radiation over time.
Spent fuel
Nuclear fuel removed from a reactor because it can no longer efficiently sustain the reaction, but still highly radioactive.
Decay curve
The exponential graph of remaining radioactive mass over time, dropping steeply then flattening.
Cooling pool
A water-filled pool where spent fuel sits after removal from a reactor to let short-lived isotopes decay and heat dissipate.

Watch it explained

  1. How it worksHow does half-life turn a decay curve into a waiting time measured in millennia?
  2. Worked exampleFind how much of a 200 gram radioactive sample is left after four half-lives.
  3. Worked exampleFind how long 80 grams of an isotope with a 30 year half-life takes to fall to 5 grams.
  4. Going furtherWhat happens to the radioactivity of spent fuel over the first 300 years in a cooling pool?

Check yourself

Your turn1 of 2
A radioactive sample starts at 379 grams. Find how much remains after 5 half-lives.

End of topic.