AP® Physics 2: Algebra-Based · Unit 15 · Topic 15.1
The de Broglie Wavelength
Every moving particle has a wavelength given by lambda = h/(mv). For everyday objects this wavelength is absurdly small, but for electrons it is large enough to matter.
Light behaves like a wave and like a particle. De Broglie's idea, proposed in 1924, was to flip that around: if waves can act like particles, maybe particles can act like waves. He proposed that any moving object has a wavelength tied to its momentum, lambda = h/p, where p = mv and h is Planck's constant, 6.63 x 10−34 J s. Double the momentum and the wavelength is cut in half. This is not a metaphor. Electrons genuinely diffract and interfere, just like light passing through a slit.
The reason nobody notices a baseball's wavelength is the size of h. Planck's constant is tiny, so unless mv is also tiny, lambda comes out far smaller than anything you could ever detect with a ruler, a slit, or any physical apparatus. An electron has a mass around 9.11 x 10−31 kg, small enough that even at ordinary speeds its wavelength lands in the range of atomic spacing, roughly 10−10 to 10−9 meters. That is why electron waves show up in real experiments and baseball waves never do.
This sets up the rest of modern physics. Once you accept that electrons have wavelengths, it makes sense that they can only exist in certain standing-wave patterns around a nucleus, which is exactly the energy-level picture used for atomic spectra. It also explains the electron microscope, which trades light for electrons to resolve far smaller structures than any optical microscope could ever manage.
Key terms
- de Broglie wavelength
- The wavelength lambda = h/(mv) associated with any moving object because of its momentum.
- Planck's constant (h)
- A fixed value, 6.63 x 10−34 J s, that sets the scale of all quantum effects.
- momentum (p)
- The product of an object's mass and velocity, p = mv.
- wave-particle duality
- The principle that both light and matter show wave behavior and particle behavior depending on the experiment.
Watch it explained
- How it worksHow does momentum set the wavelength of any particle through one short relationship?
- Worked exampleFind the de Broglie wavelength of an electron moving at 2.0 x 106 m/s.
- Worked exampleFind the wavelength of a 0.15 kg baseball thrown at 40 m/s and compare it to an atom's size.
- Going furtherHow does an electron microscope use these tiny wavelengths to beat an optical microscope?
Check yourself
End of topic.